1/ I add new car entity (carEnt)
2/ I add new Employee for Car (carEnt.EmployeeCollectionViaEmployeeOnCar.Add(new EmployeeEntity("JOHN"))
3/ I save (carEnt.Save(true))
Please check the question "How do I create a m:n relation between two entity objects?
" in the "Best practises -> How do I...?" section of the LLBLgen Pro manual.