there are a couple different ways to create the information you need. My first question is what is the db schema, and how are your enities related within LLBL? Off the top of my head these 2 examples may work... this assumes a 1:N or M:N relation between language and people.
do you want a collection of languages and their related PeopleEntities such as:
1. English
1.1 Jason
1.2 Mike
1.3 Susan
2. Spanish
2.1 Juan
2.2 Maria
this example can be created via a LanguageEntityCollection and PeoplePrefetchPath
Or do you want just a collection of people who speak a specific language (english)?
Jason
Mike
Susan
This is simple enough by declaring a new PeopleEntityCollection and New Predicate (PeopleFields.LanguageId == [the language id])
I don't think you would need an "in" clause [CompareSetPredicate()] to get the data you want.