No that's not possible at the moment, although I don't think there will be a solution, other than faking values with CASE, as IMHO there is no setting/hint to order values in such a way that NULL's are considered bigger/smaller.
The 'workaround' could be that you execute the query twice: once with a filter that filters on NULL (and no sorting, just grab the NULL values) and the second time you query with the order by and you filter NULL's out.