The TemplateBindings tab shows the templates that can be used in the generation process. This is useful only when you have custom templates that overrides the original ones, so at this tab you can move up/down the bindings to set the precedence. You cannot select a thing here, you just can reorder the precedence.
The sub-tab you have to look at is the "General Settings. Select the language of your preference, .Net4 as the platform and Adapter as template group. You also could select SelfServicing. [url description="See this"]http://llblgen.com/documentation/3.0/LLBLGen%20Pro%20RTF/hh_goto.htm#Concepts/concepts_templatesets.htm[/url] to understand the difference.
At the "Task queue to execute" sub-tab you can choose a Preset. A preset is a subset of tasks LLBLGen will execute consuming the templates to generate your code. Here just use the default one (General2010).
Read this to know more about the generation process.