How does it strongly couple the DAL to the UI any more than using POCO entities ? The UI still has to have the knowledge of the structure of the entities that it will be working with. What it does do is strongly couple both layers to LLBLGen - you need to decide for yourself if this is acceptable for you.
Personally I've never had a problem with it, the advantages gained (ie all of the nice stuff that the LLBLGen entities do for you, such as change tracking and graph management, and the fact that you don't have to continually translate your DAL entities to your UI entities and back again) far outweigh the disadvantages that come with the additional coupling.
Sorry, but I don't think any of the samples in the download area are n-tier. They are designed to demonstrate specific language features rather than overall architechture.
Matt