You don't need an expression. Expressions are like:
WHERE ShippingDate > (OrderDate + 3)
(OrderDate + 3) is an expression here).
If you want customers which have 1 order at least, you simply specify a relation collection and the Customer - Order relation and that will result in an INNER JOIN, which will filter out customers without an order
You can also use a FieldCompareSetPredicate which compares customer.CustomerID with teh customerid's in the order table (Customer.CustomerID IN (SELECT CustomerID FROM Orders)) . The FieldCompareSetPredicate is likely to be a bit faster.