So like ValidateEntityAfterLoad, but after the prefetch path has been fetched.
Do you mean you want to validate after it has been prefetched? (ValidateEntityAfterLoad should work here).
Or Do you mean you want to validate an entity after its related entities have been prefetched (i.e the entire graph has been fetched)?
For the later case I see no way than a custom validation triggered manually from your business code.
So you can write a validator and put your validation inside ValidateEntity(), which isn't used internally by the LLBLGen Pro runtime, but can be used by your own code to validate an entity in any context.
Then you should call myEntity.ValidateEntity() anywhere you like which in turn calls your validator's ValidateEntity(). (in case a validator was assigned to the entity).